New molecule-based magnets: from hexacyano to octacyanometalates

被引：68

作者：

Garde, R

Desplanches, C

Bleuzen, A

Veillet, P

Verdaguer, M

机构：

[1] Univ Paris 06, CNRS, F-75252 Paris, France

[2] Univ Paris 11, Inst Elect Fondamentale, Orsay, France

来源：

MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 1999年 / 334卷

关键词：

Prussian Blue analogs; molecular magnetism; hexacyanometalates; octacyanometalates; molecule-based magnets;

D O I：

10.1080/10587259908023353

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

Prussian blue molecule-based magnets can be designed to exhibit various magnetic properties. One of them based on chromicyanide and vanadium is a magnet at room temperature. Its properties are very sensitive to the synthetic reaction conditions, solvent effects and counterions which can be used to tune the T-c. To study the interaction between nearest metallic neighbours we explore also the influence of diffuse and high energy magnetic orbitals, i.e. 4d or 5d metallic orbitals. Two derivatives of [W-v(CN)(8)](3-) are presented.

引用

页码：587 / 595

页数：9

共 23 条

[1] ELECTRONIC STRUCTURES OF HEXACYANOMETALATE COMPLEXES [J].