Direct functionalization at the boron center of antiaromatic chloroborole

被引:78
作者
Braunschweig, Holger [1 ]
Kupfer, Thomas [1 ]
机构
[1] Univ Wurzburg, Inst Anorgan Chem, D-97074 Wurzburg, Germany
关键词
D O I
10.1039/b808483a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The presence of a reactive B-Cl bond allowed for the direct functionalization of the boron center in antiaromatic chloroborole ClBC4Ph4, thus allowing for a selective. ne tuning of the optical properties of borole derivatives and facilitating a potential new approach toward the introduction of borole moieties into the backbone of organic pi-conjugated frameworks.
引用
收藏
页码:4487 / 4489
页数:3
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