Photoredox functionalization of C-H bonds adjacent to a nitrogen atom

被引：991

作者：

Shi, Lei

Xia, Wujiong ^{[1
]}

机构：

[1] Harbin Inst Technol, State Key Lab Urban Water Resource & Environm, Harbin 150080, Peoples R China

来源：

CHEMICAL SOCIETY REVIEWS | 2012年 / 41卷 / 23期

关键词：

DEHYDROGENATIVE COUPLING REACTIONS; VISIBLE-LIGHT PHOTOCATALYSIS; ELECTRON-TRANSFER; DUAL CATALYSIS; STRATEGY; OXIDATION; EFFICIENT; RADICALS; AMINES; WATER;

D O I：

10.1039/c2cs35203f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The functionalization of C-H bonds and the visible light photoredox catalysis represent two prominent challenges in organic chemistry. In this regard, the combination of visible-light catalysis and C-H bond functionalization adjacent to a tertiary amine has been successfully developed in the past three years. In this tutorial review, we aim to give a brief overview of this issue and state the main results obtained in the reactions.

引用

页码：7687 / 7697

页数：11

共 62 条

[1] Synergistic catalysis: A powerful synthetic strategy for new reaction development
Allen, Anna E.
MacMillan, David W. C.
[J]. CHEMICAL SCIENCE, 2012, 3 (03) : 633 - 658
[2] ARTIFICIAL PHOTOSYNTHESIS - SOLAR SPLITTING OF WATER TO HYDROGEN AND OXYGEN
BARD, AJ
FOX, MA
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1995, 28 (03) : 141 - 145
[3] Catalytic enantioselective reactions driven by photoinduced electron transfer
Bauer, A
Westkämper, F
Grimme, S
Bach, T
[J]. NATURE, 2005, 436 (7054) : 1139 - 1140
[4] ALPHA-LITHIOAMINE SYNTHETIC EQUIVALENTS FROM DIPOLE-STABILIZED CARBANIONS - THE TERT-BOC GROUP AS AN ACTIVATOR FOR ALPHA'-LITHIATION OF CARBAMATES
BEAK, P
LEE, WK
[J]. TETRAHEDRON LETTERS, 1989, 30 (10) : 1197 - 1200
[5] Innate and Guided C-H Functionalization Logic
Brueckl, Tobias
Baxter, Ryan D.
Ishihara, Yoshihiro
Baran, Phil S.
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 2012, 45 (06) : 826 - 839
[6] Direct sp3 C-H bond activation adjacent to nitrogen in heterocycles
Campos, Kevin R.
[J]. CHEMICAL SOCIETY REVIEWS, 2007, 36 (07) : 1069 - 1084
[7] Carbonylation at sp3 C-H bonds adjacent to a nitrogen atom in alkylamines catalyzed by rhodium complexes
Chatani, N
Asaumi, T
Ikeda, T
Yorimitsu, S
Ishii, Y
Kakiuchi, F
Murai, S
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (51) : 12882 - 12883
[8] Ciamician G, 1912, Science, V36, P385, DOI 10.1126/science.36.926.385
[9] Visible-Light Photoredox Catalysis: Aza-Henry Reactions via C-H Functionalization
Condie, Allison G.
Gonzalez-Gomez, Jose C.
Stephenson, Corey R. J.
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (05) : 1464 - +
[10] Friedel-Crafts Amidoalkylation via Thermolysis and Oxidative Photocatalysis
Dai, Chunhui
Meschini, Francesco
Narayanam, Jagan M. R.
Stephenson, Corey R. J.
[J]. JOURNAL OF ORGANIC CHEMISTRY, 2012, 77 (09) : 4425 - 4431

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