A Cahn-Hilliard-type theory for species diffusion coupled with large elastic-plastic deformations

被引:146
作者
Anand, Lallit [1 ]
机构
[1] MIT, Dept Mech Engn, Cambridge, MA 02139 USA
基金
美国国家科学基金会;
关键词
Continuum mechanics; Diffusion; Elasticity; Plasticity; Lithium-ion batteries; LITHIUM-ION BATTERIES; STRESS; ELECTRODES; MECHANICS; CAPACITY;
D O I
10.1016/j.jmps.2012.08.001
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We develop a unified framework of balance laws and thermodynamically consistent constitutive equations which couple Cahn-Hilliard-type species diffusion with large elastic-plastic deformations of a body, and account for the swelling and phase segregation caused by the diffusing species. A potential, technologically important, area of application of the theory is in the chemo-mechanical analysis of the evolution of large stresses which develop because of the volume changes associated with the diffusion of lithium ions in the active electrode particles of lithium-ion batteries during charge-discharge cycles. (C)2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1983 / 2002
页数:20
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