Metathesis of aniline and 1,2-dihydroquinoline derivatives

被引:50
作者
Evans, P
Grigg, R [1 ]
Monteith, M
机构
[1] Univ Leeds, Sch Chem, MIDAS Ctr, Leeds LS2 9JT, W Yorkshire, England
[2] Zeneca Lifesci Mol, Huddersfield HD2 1FF, W Yorkshire, England
基金
英国工程与自然科学研究理事会;
关键词
D O I
10.1016/S0040-4039(99)00993-4
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Ring closing metathesis of N,N-diallylanilines and a related 1,2-dihydroquinoline. catalysed by Grubbs' catalyst, occurs in good yield at room temperature furnishing 3-pyrrolines and 3-piperidines, DCM and EtOAc are the solvents of choice and interesting substituent effects are identified and discussed. (C) 1999 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:5247 / 5250
页数:4
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