Molecules at close range: encapsulated solvent molecules in pyrogallol[4]arene hexameric capsules

被引：56

作者：

Avram, L ^{[1
]}

Cohen, Y ^{[1
]}

机构：

[1] Tel Aviv Univ, Raymond & Beverly Sackler Fac Exact Sci, Sch Chem, IL-69978 Tel Aviv, Israel

来源：

ORGANIC LETTERS | 2006年 / 8卷 / 02期

关键词：

D O I：

10.1021/ol052459+

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Pyrogallol[4]arenes form hexameric capsules with a large cavity and can be regarded as nanoreactors. The H-1 NMR signals of the encapsulated chloroform and benzene molecules are very complex, which may indicate that these encapsulated molecules are trapped in slightly different capsules. Co-encapsulation was found to be favored, and the ASIS effect was found to be enhanced, probably due to the close proximity and the higher molecular fraction of the benzene/chloroform complex in the capsule.

引用

页码：219 / 222

页数：4

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