Zeolite ZSM-5 with unique supermicropores synthesized using mesoporous carbon as a template

被引：300

作者：

Yang, ZX ^{[1
]}

Xia, YD ^{[1
]}

Mokaya, R ^{[1
]}

机构：

[1] Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England

来源：

ADVANCED MATERIALS | 2004年 / 16卷 / 08期

关键词：

D O I：

10.1002/adma.200306295

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A nanocasting route that utilizes well-ordered mesoporous carbon as a solid template can be used to synthesize zeolite ZSM-5 with unique supermicropores. By changing the nature of the mesoporous carbon template, the textural properties of the zeolite can be varied, and as the Figure shows, the mesoporous MZSM-5 zeolites are made up of nanocrystallites.

引用

收藏

页码：727 / +

页数：7

相关论文

共 25 条

[1] THERMOGRAVIMETRIC AND INFRARED STUDY OF THE DESORPTION OF BUTYLAMINE, CYCLOHEXYLAMINE AND PYRIDINE FROM NI-EXCHANGED AND CO-EXCHANGED MONTMORILLONITE [J].

BREEN, C .

CLAY MINERALS, 1991, 26 (04) :487-496

[2] A new MFI-type zeolite containing uniform supermicropores:: synthesis by structural transformation of CTA+-MCM-41 and application in SCR of NOx [J].

Chen, XY ;

Kawi, S .

CHEMICAL COMMUNICATIONS, 2001, (15) :1354-1355

[3] From microporous to mesoporous molecular sieve materials and their use in catalysis [J].

Corma, A .

CHEMICAL REVIEWS, 1997, 97 (06) :2373-2419

[4] In situ observation of nucleation and crystal growth in zeolite synthesis. A small-angle X-ray scattering investigation on Si-TPA-MFI [J].

de Moor, PPEA ;

Beelen, TPM ;

van Santen, RA .

JOURNAL OF PHYSICAL CHEMISTRY B, 1999, 103 (10) :1639-1650

[5]

Dong AA, 2002, ADV MATER, V14, P1506, DOI 10.1002/1521-4095(20021016)14:20<1506::AID-ADMA1506>3.0.CO

[6]

2-Z

[7] Pore size determination in modified micro- and mesoporous materials.: Pitfalls and limitations in gas adsorption data analysis [J].

Groen, JC ;

Peffer, LAA ;

Pérez-Ramírez, J .

MICROPOROUS AND MESOPOROUS MATERIALS, 2003, 60 (1-3) :1-17

[8] Dual templating of macroporous silicates with zeolitic microporous frameworks [J].

Holland, BT ;

Abrams, L ;

Stein, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (17) :4308-4309

[9] Zeolites by confined space synthesis -: characterization of the acid sites in nanosized ZSM-5 by ammonia desorption and 27Al/29Si-MAS NMR spectroscopy [J].

Jacobsen, CJH ;

Madsen, C ;

Janssens, TVW ;

Jakobsen, HJ ;

Skibsted, J .

MICROPOROUS AND MESOPOROUS MATERIALS, 2000, 39 (1-2) :393-401

[10] Mesoporous zeolite single crystals [J].

Jacobsen, CJH ;

Madsen, C ;

Houzvicka, J ;

Schmidt, I ;

Carlsson, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (29) :7116-7117