Characterization and hydrogenation of methyl oleate over Ru/TiO2, Ru-Sn/TiO2 catalysts

The hydrogenation of methyl oleate over 2%Ru/TiO2, 4.7%Sn/TiO2 and 2%Ru-4.7%Sn-TiO2 Catalysts was Studied. The catalysts were prepared by the impregnation method. The characterization techniques used were: (i) specific surface area (B.E.T. method); (ii) pore volume and mean pore diameter; (iii) thermogravimetric analysis (TGA): (iv) temperature programed reduction (TPR): (v) X-ray diffraction (DRX); and (vi) scanning electron microscopy (SEM). The results indicate that the presence of tin increases the difficulty of the ruthenium reduction, evidencing a possible metal-metal interaction. However, tin addition to the TiO2 and the catalysts calcinations did not significantly influence the values obtained for the surface area and mean pore diameter. The DRX analyses showed that the catalysts have a crystalline structure, mostly in the anatase form. The metal-support interaction occurred probably due to the formation of RuTi of Ru/TiO2 catalyst. In Ru-Sn/TiO2 catalyst, the metal-metal interaction occurs between ruthenium and tin, resulting in Ru3Sn7. The catalysts reaction revealed that tin addition in ruthenium affects the activity of catalyst considerably in the hydrogenation of methyl oleate reaction. However, the activity decrease is accompanied by a considerable increase of alcohols yield, in particular of unsaturated alcohols. (C) 2008 Elsevier B.V. All rights reserved.