Current-Free Deposition of Prussian Blue with Organic Polymers: Towards Improved Stability and Mass Production of the Advanced Hydrogen Peroxide Transducer

被引：61

作者：

Borisova, Anastasiya V. ^{[1
]}

Karyakina, Elena E. ^{[1
]}

Cosnier, Serge ^{[2
]}

Karyakin, Arkady A. ^{[1
]}

机构：

[1] Moscow MV Lomonosov State Univ, Fac Chem, Moscow 119991, Russia

[2] Univ Grenoble 1, CNRS, Dept Chim Mol, ICMG FR 2607,UMR 5250, Grenoble, France

来源：

ELECTROANALYSIS | 2009年 / 21卷 / 3-5期

关键词：

Prussian blue; Open circuit deposition; Hydrogen peroxide; Exhaled breath condensate; CARBON-FIBER MICROELECTRODE; EXHALED BREATH CONDENSATE; OXIDATIVE STRESS; MODIFIED ELECTRODES; THIN-FILMS; BIOSENSORS; REDUCTION; ELECTROCHEMISTRY; POLYPYRROLES; HYPOTHESIS;

D O I：

10.1002/elan.200804408

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

We report on a novel approach for open-circuit (current-free) deposition of Prussian blue. Synthesis of Prussian blue is carried out by reduction of ferric ferricyanide with organic molecules, which are known to form polymers upon oxidation. The proposed interfacial deposition is a result of the synthesis in the presence of electrode support due to preconcentration of precursors at the interface. The resulting modified electrodes displayed the dramatically improved operational stability in hydrogen peroxide continuous monitoring with no loss of either electrochemical or analytical performance characteristics compared to electrodes with electrochemically deposited Prussian blue. ne shown possibility to deposit stable films with regular structure in the absence of any external voltage could open new horizons for sensor science.

引用

页码：409 / 414

页数：6

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