Preparation of primary amines by the copper(I) catalyzed reaction of 4,4'-bis(trifluoromethyl)benzophenone O-methylsulfonyloxime and alkyl Grignard reagents

被引：85

作者：

Tsutsui, H ^{[1
]}

Hayashi, Y ^{[1
]}

Narasaka, K ^{[1
]}

机构：

[1] UNIV TOKYO, DEPT CHEM, GRAD SCH SCI, BUNKYO KU, TOKYO 113, JAPAN

来源：

CHEMISTRY LETTERS | 1997年 / 04期

关键词：

D O I：

10.1246/cl.1997.317

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Primary amines are prepared by the reaction of 4,4'-bis(trifluoromethyl)benzophenone O-methylsulfonyloxime and alkyl Grignard reagents in the presence of a catalytic amount of CuCN.2LiCl and the successive acid hydrolysis of the resulting N-alkylimine derivatives.

引用

页码：317 / 318

页数：2

共 15 条

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