Metal coordination to assist molecular gelation

被引：270

作者：

Fages, F ^{[1
]}

机构：

[1] Univ Aix Marseille 2, Fac Sci Luminy, UMR CNRS 6114, GCOM2, F-13288 Marseille 9, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 11期

关键词：

coordination chemistry; gels; materials science; self-assembly; supramolecular chemistry;

D O I：

10.1002/anie.200503704

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Gelling together: Molecular gels are a class of nanoscale materials based on the self-assembly of low-molecular-weight compounds. The manipulation of metal-ligand interactions offers novel opportunities to fabricate highly processable and stimuli-responsive metallogels that capitalize on the rich properties of the metal complexes (see picture).

引用

页码：1680 / 1682

页数：3

共 38 条

[1]

Abdallah DJ, 2000, ADV MATER, V12, P1237

[2] Multistimuli, multiresponsive metallo-supramolecular polymers [J].

Beck, JB ;

Rowan, SJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (46) :13922-13923

[3]

Biihler G., 2003, ANGEW CHEM, V115, P2599

[4] A metal-carbene carbohydrate amphiphile as a low-molecular-mass organometallic gelator [J].

Bühler, G ;

Feiters, MC ;

Nolte, RJM ;

Dötz, KH .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (22) :2494-2497

[5] Self-assembled peptide amphiphile nanofibers conjugated to MRI contrast agents [J].

Bull, SR ;

Guler, MO ;

Bras, RE ;

Meade, TJ ;

Stupp, SI .

NANO LETTERS, 2005, 5 (01) :1-4

[6]

Cl?rac R., 2004, ANGEW CHEM, V116, P3345

[7] Design and application of self-assembled low molecular weight hydrogels [J].

de Loos, M ;

Feringa, BL ;

van Esch, JH .

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2005, 2005 (17) :3615-3631

[8] Water gelation by small organic molecules [J].

Estroff, LA ;

Hamilton, AD .

CHEMICAL REVIEWS, 2004, 104 (03) :1201-1217

[9]

Fages F, 2005, TOP CURR CHEM, V256, P1

[10] Low molecular weight gelator containing β-diketonato ligands:: Stabilization of gels by metal coordination [J].

Hanabusa, K ;

Maesaka, Y ;

Suzuki, M ;

Kimura, M ;

Shirai, H .

CHEMISTRY LETTERS, 2000, (10) :1168-1169

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