Improving the photophysical properties of copper(I) bis(phenanthroline) complexes

被引：249

作者：

Lavie-Cambot, Aurelie ^{[1
]}

Cantuel, Martine ^{[1
]}

Leydet, Yoann ^{[1
]}

Jonusauskas, Gediminas ^{[2
]}

Bassani, Dario M. ^{[1
]}

McClenaghan, Nathan D. ^{[1
]}

机构：

[1] Univ Bordeaux 1, CNRS, Inst Mol Sci, Grp Nanostruct Organ,UMR 5255, F-33405 Talence, France

[2] Univ Bordeaux 1, CNRS, UMR 5798, Ctr Phys Mol Opt & Hertzienne, F-33405 Talence, France

来源：

COORDINATION CHEMISTRY REVIEWS | 2008年 / 252卷 / 23-24期

关键词：

Copper; Phenanthroline; Excited-state equilibration; Energy transfer; Luminescence lifetimes; Supramolecular photochemistry/photophysics;

D O I：

10.1016/j.ccr.2008.03.013

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Homoleptic copper(I) bis(2,9-dialkyl-1,10-phenanthroline) units, as well as a range of related heteroleptic species, represent popular choices for building blocks in the construction of supramolecular edifices and photo- and electroactive devices. The photophysical properties of these traditionally underperforming luminescent complexes can be dramatically modified in a qualitatively predictable fashion through ligand design, the use of bichromophoric ligands, and by reconstitution of the primary coordination sphere. An overview of key excited-state processes established in these complexes is presented, with particular emphasis on recent developments and insights. as well as ramifications for developing successful strategies to prolong luminescence lifetimes and increase quantum yields. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：2572 / 2584

页数：13

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