Online monitoring of biogenic nitric oxide with a QC laser-based Faraday modulation technique

被引:35
作者
Ganser, H
Horstjann, M
Suschek, CV
Hering, P
Mürtz, M
机构
[1] Univ Dusseldorf, Inst Lasermed, D-40225 Dusseldorf, Germany
[2] Univ Dusseldorf, Abt Immunobiol, D-40225 Dusseldorf, Germany
来源
APPLIED PHYSICS B-LASERS AND OPTICS | 2004年 / 78卷 / 3-4期
关键词
D O I
10.1007/s00340-003-1379-0
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
Online sensing of nitric oxide traces based on a cw quantum cascade laser, operating near 5.2 mum, is reported. We utilized a Faraday modulation technique which provides unique selectivity since it exploits the magnetic moment of nitric oxide (NO) molecules. The minimum detectable NO concentration was found to be 4 ppb (sampling time: 10 s). Continuous monitoring of the NO release from nitrite solutions and human sweat samples is described. Detectable NO release rates are down to 10 pmol/s. We compare NO generation induced by a chemical, and by exposure to ultra-violet radiation.
引用
收藏
页码:513 / 517
页数:5
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