Solvent-assisted mechanochemistry

被引：336

作者：

Bowmaker, Graham A. ^{[1
]}

机构：

[1] Univ Auckland, Sch Chem Sci, Auckland 1142, New Zealand

来源：

CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 04期

关键词：

CRYSTAL-STRUCTURES; VIBRATIONAL SPECTROSCOPY; METAL-COMPLEXES; COPPER(I) THIOCYANATE; DICARBOXYLIC-ACIDS; SOLID REACTIONS; PARTICLE-SIZE; CO-CRYSTAL; ADDUCTS; COCRYSTALS;

D O I：

10.1039/c2cc35694e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The literature on solvent-assisted mechanochemistry is reviewed with a view to linking observations concerning the applicability of the technique to theories of its mechanism, and summarizing the advantages and limitations of the technique when applied to a variety of different reaction types. Previously unnoticed links between "solvent-free'' and solvent-assisted reaction mechanisms are presented, and reasons why the method should be considered more widely by synthetic chemists are given.

引用

页码：334 / 348

页数：15

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