Bifunctional oxygen electrode with corrosion-resistive gas diffusion layer for unitized regenerative fuel cell

被引:102
作者
Song, SD [1 ]
Zhang, HM [1 ]
Ma, XP [1 ]
Shao, ZG [1 ]
Zhang, YN [1 ]
Yi, BL [1 ]
机构
[1] Chinese Acad Sci, Dalian Inst Chem Phys, Fuel Cell R&D Ctr, Dalian 116023, Liaoning, Peoples R China
关键词
unitized regenerative fuel cells; gas diffusion layer; micro-porous layer; water electrolysis; bifunctional oxygen electrode;
D O I
10.1016/j.elecom.2006.01.001
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
To develop the unitized regenerative fuel cell (URFC) with low cost and high performance, a novel bifunctional oxygen electrode with a thin-film electrocatalyst layer and a corrosion-resistive gas diffusion layer (GDL) prepared by the carbon paper backing and a protective micro-porous layer (MPL) was developed. The protective MPL was made of the IrO2 deposited fine Ti powders. The cycle performance and polarization curves for both fuel cell and water electrolysis modes of URFC operation were investigated. The cycle performance of the URFC was stable during 20 cycles. It exhibits a high fuel cell performance as good as the URFC using the conventional GDL and a much higher water electrolysis performance. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:399 / 405
页数:7
相关论文
共 20 条
[2]   Combinatorial discovery of bifunctional oxygen reduction - water oxidation electrocatalysts for regenerative fuel cells [J].
Chen, GY ;
Delafuente, DA ;
Sarangapani, S ;
Mallouk, TE .
CATALYSIS TODAY, 2001, 67 (04) :341-355
[3]  
Damjanovic A., 1966, ELECTROCHIM ACTA, V11, P791, DOI [DOI 10.1016/0013-4686(66)87056-1, 10.1016/0013-4686, DOI 10.1016/0013-4686, 10.1016/0013-4686(66)87056-1]
[4]   Impedance investigations of the mechanism of oxygen evolution on composite electrodes [J].
Darowicki, K ;
Orlikowski, J .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1999, 146 (02) :663-668
[5]   Oxygen evolution in acid solution on IrO2+TiO2 ceramic films. A study by impedance, voltammetry and SEM [J].
daSilva, LA ;
Alves, VA ;
daSilva, MAP ;
Trasatti, S ;
Boodts, JFC .
ELECTROCHIMICA ACTA, 1997, 42 (02) :271-281
[6]   Surface and electrocatalytic properties of ternary oxides Ir0.3Ti(0.7-x)PtxO2. Oxygen evolution from acidic solution [J].
DaSilva, LA ;
Alves, VA ;
Trasatti, S ;
Boodts, JFC .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1997, 427 (1-2) :97-104
[7]   Electrocatalytic properties of ternary oxide mixtures of composition Ru0.3Ti(0.7-x)CexO2: Oxygen evolution from acidic solution [J].
DeFaria, LA ;
Boodts, JFC ;
Trasatti, S .
JOURNAL OF APPLIED ELECTROCHEMISTRY, 1996, 26 (11) :1195-1199
[8]   A UNITIZED APPROACH TO REGENERATIVE SOLID POLYMER ELECTROLYTE FUEL-CELLS [J].
DHAR, HP .
JOURNAL OF APPLIED ELECTROCHEMISTRY, 1993, 23 (01) :32-37
[9]   Oxygen evolution reaction on IrO2-based DSA® type electrodes:: kinetics analysis of Tafel lines and EIS [J].
Hu, JM ;
Zhang, JQ ;
Cao, CN .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2004, 29 (08) :791-797
[10]   Sub-stoichiometric titanium oxide-supported platinum electrocatalyst for polymer electrolyte fuel cells [J].
Ioroi, T ;
Siroma, Z ;
Fujiwara, N ;
Yamazaki, S ;
Yasuda, K .
ELECTROCHEMISTRY COMMUNICATIONS, 2005, 7 (02) :183-188