A convenient preparation of 3-substituted furans: Synthesis of perillene and dendrolasin

被引:24
作者
Barma, DK
Kundu, A
Baati, R
Mioskowski, C
Falck, JR [1 ]
机构
[1] Univ Texas, SW Med Ctr, Dept Biochem, Dallas, TX 75390 USA
[2] Univ Louis Pasteur Strasbourg 1, Fac Pharm, CNRS, Lab Synth Bioorgan, F-67401 Illkirch Graffenstaden, France
关键词
D O I
10.1021/ol025708s
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
[GRAPHICS] A variety of 3-substituted furans, including the natural products perillene and dendrolasin, are obtained in good yield via reductive annulation of 1,1,1-trichloroethyl propargyl ethers using catalytic Cr(II) regenerated by Mn/TMSCl.
引用
收藏
页码:1387 / 1389
页数:3
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