Phase equilibria of alkanes in natural gas systems .3. Alkanes in carbon dioxide

被引:41
作者
Chandler, K
Pouillot, FLL
Eckert, CA
机构
[1] GEORGIA INST TECHNOL,SCH CHEM ENGN,ATLANTA,GA 30332
[2] GEORGIA INST TECHNOL,CTR SPECIALTY SEPARAT,ATLANTA,GA 30332
关键词
D O I
10.1021/je950138a
中图分类号
O414.1 [热力学];
学科分类号
摘要
A chromatographic technique was used to measure experimental capacity factors for the n-alkanes from C9H20 to C36H74 in CO2 from 308.2 to 348.2 K and from 100 to 240 bar. Infinite dilution activity coefficients, gamma(i)(infinity), were calculated for the solid n-alkanes (C24H50 to C36H74) utilizing regular solution theory to characterize the stationary phase. This allowed the estimation of solubilities from capacity factors for the solid n-alkanes in CO2.
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页码:6 / 10
页数:5
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