Preparation, characterization, and properties of chitosan-g-poly(vinyl alcohol) copolymer

被引：19

作者：

Huang, MF ^{[1
]}

Fang, Y ^{[1
]}

机构：

[1] Univ Sci & Technol China, Dept Polymer Sci & Engn, Anhua 230026, Peoples R China

来源：

BIOPOLYMERS | 2006年 / 81卷 / 03期

关键词：

chitosan; chitosan-g-PVA; graft copolymers; esterification; thermal property;

D O I：

10.1002/bip.20383

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

The graft copolymer chitosan-g-poly(vinyl alcohol), with nontoxicity, biodegradability, and biocompatibility, was prepared by a novel method. The copolymer with porous net structure was observed by scanning electron microscopy (SEM). It is a potential method to combine chitosan with the synthetic polymers. The grafting reactions were conducted with various poly(vinyl alcohol) (PVA)/6-0-succinate-N-phthaloyl-chitosan (PHCSSA) feed ratios to obtain chitosan-g-poly(vinyl alcohol) copolymers with various PVA contents. The chemical structure of the chitosan-g-poly(vinyl alcohol) was characterized by Fourier transform infrared and nuclear magnetic resonance (NMR) spectroscopy. Differential scanning calorimetry (DSC), X-ray diffraction (XRD), and SEM were also detected to characterize the copolymer. (c) 2005 Wiley Periodicals, Inc.

引用

页码：160 / 166

页数：7

共 28 条

[1] Controlled release of clozapine through chitosan microparticles prepared by a novel method [J].

Agnihotri, SA ;

Aminabhavi, TM .

JOURNAL OF CONTROLLED RELEASE, 2004, 96 (02) :245-259

[2] Physico-chemical studies of chitosan-poly(vinyl alcohol) blends plasticized with sorbitol and sucrose [J].

Arvanitoyannis, I ;

Kolokuris, I ;

Nakayama, A ;

Yamamoto, N ;

Aiba, S .

CARBOHYDRATE POLYMERS, 1997, 34 (1-2) :9-19

[3]

Bahrami SB, 2003, IRAN POLYM J, V12, P139

[4] PROSTAGLANDIN-E1-IMMOBILIZED POLY(VINYL ALCOHOL)-BLENDED CHITOSAN MEMBRANES - BLOOD COMPATIBILITY AND PERMEABILITY PROPERTIES [J].

CHANDY, T ;

SHARMA, CP .

JOURNAL OF APPLIED POLYMER SCIENCE, 1992, 44 (12) :2145-2156

[5] Properties of the poly(vinyl alcohol)/chitosan blend and its effect on the culture of fibroblast in vitro [J].

Chuang, WY ;

Young, TH ;

Yao, CH ;

Chiu, WY .

BIOMATERIALS, 1999, 20 (16) :1479-1487

[6] Structures and thermal properties of chitosan-modified poly(methyl methacrylate) [J].

Don, TM ;

Hsu, SC ;

Chiu, WY .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2001, 39 (10) :1646-1655

[7] Review of vinyl graft copolymerization featuring recent advances toward controlled radical-based reactions and illustrated with chitin/chitosan trunk polymers [J].

Jenkins, DW ;

Hudson, SM .

CHEMICAL REVIEWS, 2001, 101 (11) :3245-3273

[8]

Jeong MG, 2004, POLYM-KOREA, V28, P253

[9] CHARACTERIZATION OF POLY(METHYL METHACRYLATE)-GRAFT-POLYSTYRENE PREPARED FROM METHACRYLOYLOXYETHYL POLYSTYRENE MACROMONOMER [J].

KIKUCHI, A ;

NOSE, T .

POLYMER, 1995, 36 (14) :2781-2786

[10] PROPERTIES AND SWELLING CHARACTERISTICS OF CROSS-LINKED POLY(VINYL ALCOHOL) CHITOSAN BLEND MEMBRANE [J].

KIM, JH ;

KIM, JY ;

LEE, YM ;

KIM, KY .

JOURNAL OF APPLIED POLYMER SCIENCE, 1992, 45 (10) :1711-1717

← 1 2 3 →