Degree of aggregation of indocyanine green in aqueous solutions determined by Mie scattering

被引:21
作者
Weigand, R [1 ]
Rotermund, F [1 ]
Penzkofer, A [1 ]
机构
[1] UNIV REGENSBURG,INST EXPT & ANGEW PHYS 2,D-93040 REGENSBURG,GERMANY
关键词
D O I
10.1016/S0301-0104(97)00150-X
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Indocyanine green in water and aqueous NaCl solutions forms large J-aggregates. The degree of aggregation is estimated by Rayleigh scattering and Mie scattering analysis. The refractive index of the aggregates responsible for scattering is deduced from an aggregate absorption cross-section spectrum using the Kramers-Kronig relations. The average degree of aggregation for indocyanine green in water is found to be of the order of 10(7) while it rises to 10(9) for indocyanine green in 0.01 molar aqueous NaCl solution. (C) 1997 Elsevier Science B.V.
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页码:373 / 384
页数:12
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