A host-guest complex between a metal-organic cyclotriveratrylene analog and a polyoxometalate:: [Cu6(4,7-phenanthroline)8(MeCN)4]2PM12O40 (M = Mo or W)

被引：106

作者：

Knaust, JM ^{[1
]}

Inman, C ^{[1
]}

Keller, SW ^{[1
]}

机构：

[1] Univ Missouri, Dept Chem, Columbia, MO 65211 USA

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 05期

关键词：

D O I：

10.1039/b309255k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis and crystal structure of Cu-6(4,7-phenanthroline)(8)(MeCN)(4)(6+) a novel Cu(I)-molecular hexamer is described in which the metal cations and phenanthroline molecules self-assemble into a dimer of shallow triangular-shaped bowls, within which are located large spherical polyoxometalate anions PM12O403- (M=Mo or W).

引用

页码：492 / 493

页数：2

共 20 条

[1]

ATWOOD JL, 1991, CATION BINDING MACRO, P581

[2]

ATWOOD JL, 1997, SUPRAMOL CHEM, P148

[3] Fine-tuning the ring-size of metallacyclophanes:: A rational approach to molecular pentagons [J].