Synthetic applications of the cyclic iminocarbonate rearrangement:: enantioselective syntheses of chloramphenicol and 4-epi-cytoxazone

被引：55

作者：

Park, JN

Ko, SY ^{[1
]}

Koh, HY

机构：

[1] Ewha Womans Univ, Dept Chem, Seoul 120750, South Korea

[2] Ewha Womans Univ, Div Mol Life Sci, Seoul 120750, South Korea

[3] Korea Inst Sci & Technol, Biochem Res Ctr, Seoul 130650, South Korea

来源：

TETRAHEDRON LETTERS | 2000年 / 41卷 / 29期

关键词：

enantioselective synthesis; cyclic iminocarbonate rearrangement; regioselection; chloramphenicol; 4-epi-cytoxazone;

D O I：

10.1016/S0040-4039(00)00878-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Chloramphenicol and 4-epi-cytoxazone have been enantioselectively synthesized using the asymmetric dihydroxylation and the cyclic iminocarbonate rearrangement as key steps. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：5553 / 5556

页数：4

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