Cycloaddition of aromatic imines to a ruthenium butatrienylidene complex: Synthesis of 4-ethynylquinoline and 1-azabuta-1,3-diene complexes

被引:36
作者
Bruce, MI [1 ]
Hinterding, P [1 ]
Ke, MZ [1 ]
Low, PJ [1 ]
Skelton, BW [1 ]
White, AH [1 ]
机构
[1] UNIV WESTERN AUSTRALIA,DEPT CHEM,NEDLANDS,WA 6907,AUSTRALIA
关键词
D O I
10.1039/a700663b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Reactions of aromatic imines with the putative butatrienylidene-ruthenium cation [Ru(C=C=C=CH2)(PPh(3))(2)(eta-C5H5)](+) gives complexes containing either 4-ethynylquinoline or 1-azabuta-1,3-diene ligands; the molecular structures of [Ru(C=CC(9)H(4)MeN)(PPh(3))(2)(eta-C5H5)] and [Ru{C=CC(CH=CHPh)=N(C6H4NO2-3)}(PPh(3))(2)(eta-C5H5)] are reported.
引用
收藏
页码:715 / 716
页数:2
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