Self-organization of spherical aggregates of palladium nanoparticles with a cubic silsesquioxane

被引:87
作者
Naka, K [1 ]
Itoh, H [1 ]
Chujo, Y [1 ]
机构
[1] Kyoto Univ, Grad Sch Engn, Dept Polymer Chem, Sakyo Ku, Kyoto 6068501, Japan
关键词
D O I
10.1021/nl025713p
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Uniform spherical aggregates of palladium nanoparticles with a mean diameter of 70 nm were produced by stirring of palladium(II) acetate with octa(3-aminopropyi)octasilsesquioxane octahydrochloride (1) as a cubic-linker in methanol at room temperature via self-organized spherical templates of palladium ions and 1. Transmission electron microscopy investigation showed that the highly ordered spherical aggregates were composed of the palladium nanoparticles with a size of 4.0 nm.
引用
收藏
页码:1183 / 1186
页数:4
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共 22 条
[1]   Three-dimensional self-assembly of gold nanocolloids in spheroids due to dialysis in the presence of sodium mercaptoacetate [J].
Adachi, E .
LANGMUIR, 2000, 16 (16) :6460-6463
[2]   Self-assembly of a two-dimensional superlattice of molecularly linked metal clusters [J].
Andres, RP ;
Bielefeld, JD ;
Henderson, JI ;
Janes, DB ;
Kolagunta, VR ;
Kubiak, CP ;
Mahoney, WJ ;
Osifchin, RG .
SCIENCE, 1996, 273 (5282) :1690-1693
[3]   Nanocomposite materials for optical applications [J].
Beecroft, LL ;
Ober, CK .
CHEMISTRY OF MATERIALS, 1997, 9 (06) :1302-1317
[4]   Self-assembly of nanoparticles into structured spherical and network aggregates [J].
Boal, AK ;
Ilhan, F ;
DeRouchey, JE ;
Thurn-Albrecht, T ;
Russell, TP ;
Rotello, VM .
NATURE, 2000, 404 (6779) :746-748
[5]   NOVEL GOLD-DITHIOL NANO-NETWORKS WITH NONMETALLIC ELECTRONIC-PROPERTIES [J].
BRUST, M ;
BETHELL, D ;
SCHIFFRIN, DJ ;
KIELY, CJ .
ADVANCED MATERIALS, 1995, 7 (09) :795-&
[6]   PREPARATION AND PROPERTIES OF TAILORED MORPHOLOGY, MONODISPERSE COLLOIDAL SILICA CADMIUM-SULFIDE NANOCOMPOSITES [J].
CHANG, SY ;
LIU, L ;
ASHER, SA .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (15) :6739-6744
[7]   Organic/inorganic hybrid composites from cubic silsesquioxanes [J].
Choi, J ;
Harcup, J ;
Yee, AF ;
Zhu, Q ;
Laine, RM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (46) :11420-11430
[8]   Amine and ester-substituted silsesquioxanes: synthesis, characterization and use as a core for starburst dendrimers [J].
Feher, FJ ;
Wyndham, KD .
CHEMICAL COMMUNICATIONS, 1998, (03) :323-324
[9]   Hybrid organic-inorganic thermoplastics: Styryl-based polyhedral oligomeric silsesquioxane polymers [J].
Haddad, TS ;
Lichtenhan, JD .
MACROMOLECULES, 1996, 29 (22) :7302-7304
[10]   Pressure/temperature phase diagrams and superlattices of organically functionalized metal nanocrystal monolayers: The influence of particle size, size distribution, and surface passivant [J].
Heath, JR ;
Knobler, CM ;
Leff, DV .
JOURNAL OF PHYSICAL CHEMISTRY B, 1997, 101 (02) :189-197