Oxidative dehydrogenation of ethylbenzene with carbon dioxide over zeolite-supported iron oxide catalysts

被引：24

作者：

Park, MS ^{[1
]}

Chang, JS ^{[1
]}

Kim, DS ^{[1
]}

Park, SE ^{[1
]}

机构：

[1] Korea Res Inst Chem Technol, Catalysis Ctr Mol Engn, KRICT, Taejon 305600, South Korea

来源：

RESEARCH ON CHEMICAL INTERMEDIATES | 2002年 / 28卷 / 05期

关键词：

D O I：

10.1163/156856702760346879

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Oxidative dehydrogenation of ethylbenzene with carbon dioxide was carried out over ZSM-5 zeolite-supported iron oxide catalysts. In the presence of carbon dioxide, ethylbenzene was predominantly converted into styrene by oxidation. It was found that carbon dioxide in this reaction plays a role as a soft oxidant to greatly improve catalytic activity. An active phase for the dehydrogenation with carbon dioxide was suggested as rather reduced and isolated magnetite-like phase having oxygen deficiency in zeolite matrix.

引用

页码：461 / 469

页数：9

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