Convenient and efficient Pd-catalyzed regioselective oxyfunctionalization of terminal olefins by using molecular oxygen as sole reoxidant

被引：211

作者：

Mitsudome, T ^{[1
]}

Umetani, T ^{[1
]}

Nosaka, N ^{[1
]}

Mori, K ^{[1
]}

Mizugaki, T ^{[1
]}

Ebitani, K ^{[1
]}

Kaneda, K ^{[1
]}

机构：

[1] Osaka Univ, Grad Sch Engn Sci, Toyonaka, Osaka 5608531, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 03期

关键词：

acetoxylation; alkenes; oxygen; palladium; Wacker oxidation;

D O I：

10.1002/anie.200502886

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Just the one: The combination of palladium dichloride and N,N-dimethylacetamide (DMA) constitutes a highly efficient and reusable catalytic system, which uses molecular oxygen as the sole reoxidant for liquid-phase Wacker oxidation and acetoxylation of terminal olefins to the corresponding methyl ketones and linear allylic acetates, respectively (see scheme). © 2006 Wiley-VCH Verlag GmbH © Co. KGaA.

引用

页码：481 / 485

页数：5

共 41 条

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