Dentrite-free electrochemical deposition of Li-Na alloys from an ionic liquid electrolyte

被引：46

作者：

Doyle, Kevin P. ^{[1
]}

Lang, Christopher M. ^{[1
]}

Kim, Ketack ^{[1
]}

Kohl, Paul A. ^{[1
]}

机构：

[1] Georgia Inst Technol, Atlanta, GA 30332 USA

来源：

JOURNAL OF THE ELECTROCHEMICAL SOCIETY | 2006年 / 153卷 / 07期

关键词：

D O I：

10.1149/1.2199444

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The deposition of Li-Na alloys from an ionic liquid medium has been demonstrated and evaluated with respect to dendrite growth, oxidation potential, and stability. The maximum coulombic efficiency for the reoxidation of the Li-Na alloy was found to be 91%. The conductivity of the ionic liquid medium containing the alloy salts was 364-466 mu S/cm(2). Upon addition of sodium to the lithium-ion electrolyte, a Li-Na alloy was deposited (mA/cm(2) current density range) that appears to suppress dendrite formation. (c) 2006 The Electrochemical Society.

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收藏

页码：A1353 / A1357

页数：5

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