Photoluminescent Mn4 Single-Molecule Magnet

被引：58

作者：

Beedle, Christopher C. ^{[1
]}

Stephenson, Casey J. ^{[1
]}

Heroux, Katie J. ^{[1
]}

Wernsdorfer, Wolfgang ^{[2
]}

Hendrickson, David N. ^{[1
]}

机构：

[1] Univ Calif San Diego, Dept Chem & Biochem, La Jolla, CA 92093 USA

[2] CNRS, Inst Neel, Grenoble 9, France

来源：

INORGANIC CHEMISTRY | 2008年 / 47卷 / 23期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1021/ic801485k

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis of [Mn-4(anca)(4)(Hmdea)(2)(mdea)(2)]center dot 2CHCl(3) (1) is reported along with room temperature fluorescence, UV-vis, and NMR spectra. Direct current magnetization versus field data reveal a S = 8 ground state. Quantized steps in temperature- and field-dependent magnetization versus field hysteresis loops confirm single-molecule magnet behavior.

引用

页码：10798 / 10800

页数：3

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