Evaluation of data on the kinetics of isothermal polymer crystallization .2.

被引:4
作者
Lambrigger, M
机构
[1] Lab. für Festkörperphysik, Swiss Fed. Institute of Technology
关键词
D O I
10.1002/pen.11689
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The kinetic crystallization model of Avrami is generally accepted as a starling point for the analysis of isothermal polymer crystallization. In a previous communication, the author has shown that data of isothermal crystallization experiments can be evaluated together with the help of Avrami master curves, if Vie Avrami index n is larger than one. These Avrami master curves have been obtained by scaling the three-parameter Avrami equation functions theta(t) with the time-values of its inflection points. In this work, alternative Avrami master curves will be displayed; they are obtained by scaling theta(t) with the mean-time (t) over bar = integral(0)(1) t d theta. These alternative Avrami master curves can be constructed for every Avrami index n > 0.
引用
收藏
页码:460 / 462
页数:3
相关论文
共 10 条
[1]   Granulation, Phase Change, and Microstructure - Kinetics of Phase Change. III [J].
Avrami, M .
JOURNAL OF CHEMICAL PHYSICS, 1941, 9 (02) :177-184
[2]   Kinetics of phase change I - General theory [J].
Avrami, M .
JOURNAL OF CHEMICAL PHYSICS, 1939, 7 (12) :1103-1112
[3]  
Avrami M., 1940, J CHEM PHYS, V8, P212, DOI [10.1063/1.1750631, DOI 10.1063/1.1750631]
[4]  
BUKHINA MF, 1993, NATO ADV SCI INST SE, V405, P521
[5]   QUIESCENT POLYMER CRYSTALLIZATION - MODELING AND MEASUREMENTS [J].
CHAN, TW ;
ISAYEV, AI .
POLYMER ENGINEERING AND SCIENCE, 1994, 34 (06) :461-471
[6]  
HARTLEY FD, 1954, INT S MACR CHEM MIL, P577
[7]   A NUMERICAL-METHOD FOR THE EVALUATION OF DATA ON THE KINETICS OF POLYMER CRYSTALLIZATION [J].
LAMBRIGGER, M ;
MAYER, J ;
THOMAS, RM ;
TOMKA, I .
POLYMER BULLETIN, 1990, 23 (03) :271-278
[8]   Evaluation of data on the kinetics of isothermal polymer crystallization [J].
Lambrigger, M .
POLYMER ENGINEERING AND SCIENCE, 1996, 36 (01) :98-99
[9]  
LAMBRIGGER M, UNPUB
[10]   A NEW METHOD FOR FOLLOWING RAPID RATES OF CRYSTALLIZATION .1. POLY(HEXAMETHYLENE ADIPAMIDE) [J].
MAGILL, JH .
POLYMER, 1961, 2 (02) :221-233