Understanding the failure of direct C-C coupling in the zeolite-catalyzed methanol-to-olefin process

被引：211

作者：

Lesthaeghe, D

Van Speybroeck, V

Marin, GB

Waroquier, M

机构：

[1] Univ Ghent, Ctr Mol Modeling, B-9000 Ghent, Belgium

[2] Univ Ghent, Lab Petrochem Tech, B-9000 Ghent, Belgium

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 11期

关键词：

D O I：

10.1002/anie.200503824

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) You are the weakest link, goodbye! Many individual steps of the direct mechanisms in the methanol-to-olefin process are tied together in an integrated scheme, allowing a simple identification of the weakest links. Calculations show that a combined pathway from methanol directly to ethylene does not exist and no C-C bond can be formed directly. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

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页码：1714 / 1719

页数：6

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