Ytterbium(III) trifluoromethanesulfonate catalyzed high pressure reaction of epoxides with indole. An enantioselective synthesis of (+)-diolmycin A2

被引:63
作者
Kotsuki, H
Teraguchi, M
Shimomoto, N
Ochi, M
机构
[1] Department of Chemistry, Faculty of Science, Kochi University, Kochi 780, Akebono-cho
关键词
D O I
10.1016/0040-4039(96)00670-3
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Epoxide opening reactions with indole are efficiently accelerated under high pressure conditions in the presence of a catalytic amount of ytterbium(III) trifluoromethanesulfonate to afford tryptophol derivatives. The procedure is successfully applied for an enantioselective synthesis of (+)-diolmycin A2. Copyright (C) 1996 Elsevier Science Ltd
引用
收藏
页码:3727 / 3730
页数:4
相关论文
共 20 条