Efficient intramolecular β-mannoside formation using m-xylylene and isophthaloyl derivatives as rigid spacers

被引：31

作者：

Abdel-Rahman, AAH

El Ashry, EH

Schmidt, RR ^{[1
]}

机构：

[1] Univ Konstanz, Dept Chem, Fach M725, D-78457 Constance, Germany

[2] Univ Alexandria, Fac Sci, Dept Chem, Alexandria, Egypt

来源：

CARBOHYDRATE RESEARCH | 2002年 / 337卷 / 03期

关键词：

glycosides; beta-mannopyranosides; synthesis; intramolecular glycosidation; hetaryl thioglycosides;

D O I：

10.1016/S0008-6215(01)00306-8

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

A series of mannosyl donors linked via position 2 to an in-xylylene or an isophthaloyl spacer which was connected to the position 6 of a glucoside acceptor afforded, via intramolecular glycosylation, the corresponding disaccharides with high P anomeric ratio. (C) 2002 Elsevier Science Ltd. All rights reserved.

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页码：195 / 206

页数：12

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