Silylation as a new strategy of the use of aliphatic nitro compounds in organic synthesis

被引：18

作者：

Tartakovsky, VA ^{[1
]}

Ioffe, SL ^{[1
]}

Dilman, AD ^{[1
]}

Tishkov, AA ^{[1
]}

机构：

[1] Russian Acad Sci, ND Zelinsky Inst Organ Chem, Moscow 119991, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2001年 / 50卷 / 11期

关键词：

aliphatic nitro compounds; silylation; organic synthesis; elimination; cyclization; cross-coupling; cycloaddition; silyl nitronates; N; N-bis(silyloxy)enamines; conjugated nitrosoalkenes; oximes; ene oximes; ene nitriles;

D O I：

10.1023/A:1015056024675

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Silylation of aliphatic nitro compounds is considered as a versatile multistage process. Due to activation of the beta- and gamma-carbon atoms of the initial nitro substrates, these reactions give rise to a series of products untypical of the traditional chemistry of nitro compounds. A new redox process proposed in the present study involves controlled incomplete reduction of the nitro group with simultaneous oxidation of the carbon skeleton of the initial aliphatic nitro compound.

引用

页码：1936 / 1948

页数：13

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