Gold clusters on oxygen plasma functionalized carbon nanotubes: XPS and TEM studies

被引:90
作者
Felten, A. [1 ]
Bittencourt, C. [1 ]
Pireaux, J. J. [1 ]
机构
[1] Fac Univ Notre Dame Paix, Lab Interdisciplinaire Spect Elect, B-5000 Namur, Belgium
关键词
D O I
10.1088/0957-4484/17/8/026
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Oxygen plasma treated multi-walled carbon nanotubes (MWCNTs) have been decorated with gold nanoclusters by thermal evaporation. Transmission electron microscopy (TEM) shows that the nature and extent of gold coverage can be varied by simultaneously changing the parameters used for the plasma treatment and the gold evaporation time. The evaporated gold clusters on oxygen plasma treated MWCNTs have a more dense distribution than the clusters evaporated on as-synthesized MWCNTs. Analyses of the valence band and the core levels by x-ray photoelectron spectroscopy (XPS) suggest poor charge transfer between the gold clusters and the MWCNTs.
引用
收藏
页码:1954 / 1959
页数:6
相关论文
共 33 条
[1]   Work functions and surface functional groups of multiwall carbon nanotubes [J].
Ago, H ;
Kugler, T ;
Cacialli, F ;
Salaneck, WR ;
Shaffer, MSP ;
Windle, AH ;
Friend, RH .
JOURNAL OF PHYSICAL CHEMISTRY B, 1999, 103 (38) :8116-8121
[2]  
AMINUR RGM, 2005, SMALL, V5, P527
[3]  
AMITESH M, 2004, CHEM PHYS LETT, V395, P7
[4]   X-ray photoemission spectroscopy study of fluorinated single-walled carbon nanotubes [J].
An, KH ;
Heo, JG ;
Jeon, KG ;
Bae, D ;
Jo, CS ;
Yang, CW ;
Park, CY ;
Lee, YH ;
Lee, YS ;
Chung, YS .
APPLIED PHYSICS LETTERS, 2002, 80 (22) :4235-4237
[5]   Functionalization of carbon nanotubes by electrochemical reduction of aryl diazonium salts: A bucky paper electrode [J].
Bahr, JL ;
Yang, JP ;
Kosynkin, DV ;
Bronikowski, MJ ;
Smalley, RE ;
Tour, JM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (27) :6536-6542
[6]   Alloy formation of supported gold nanoparticles at their transition from clusters to solids:: Does size matter? -: art. no. 016804 [J].
Boyen, HG ;
Ethirajan, A ;
Kästle, G ;
Weigl, F ;
Ziemann, P ;
Schmid, G ;
Garnier, MG ;
Büttner, M ;
Oelhafen, P .
PHYSICAL REVIEW LETTERS, 2005, 94 (01)
[7]   Photoconductivity study of modified carbon nanotube/oxotitanium phthalocyanine composites [J].
Cao, L ;
Chen, HZ ;
Wang, M ;
Sun, JZ ;
Zhang, XB ;
Kong, FZ .
JOURNAL OF PHYSICAL CHEMISTRY B, 2002, 106 (35) :8971-8975
[8]   Adsorption of NH3 and NO2 molecules on carbon nanotubes [J].
Chang, H ;
Lee, JD ;
Lee, SM ;
Lee, YH .
APPLIED PHYSICS LETTERS, 2001, 79 (23) :3863-3865
[9]   Plasma activation of carbon nanotubes for chemical modification [J].
Chen, QD ;
Dai, LM ;
Gao, M ;
Huang, SM ;
Mau, A .
JOURNAL OF PHYSICAL CHEMISTRY B, 2001, 105 (03) :618-622
[10]   Extreme oxygen sensitivity of electronic properties of carbon nanotubes [J].
Collins, PG ;
Bradley, K ;
Ishigami, M ;
Zettl, A .
SCIENCE, 2000, 287 (5459) :1801-1804