The remarkable catalytic activity of alkali-metal alkoxide clusters in the ester interchange reaction

被引：58

作者：

Stanton, MG ^{[1
]}

Gagne, MR ^{[1
]}

机构：

[1] UNIV N CAROLINA,DEPT CHEM,CHAPEL HILL,NC 27599

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1997年 / 119卷 / 21期

关键词：

APROTIC-SOLVENTS; WEAKLY POLAR; TETRAHYDROFURAN; AGGREGATION; SODIUM;

D O I：

10.1021/ja970556v

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

页码：5075 / 5076

页数：2

共 16 条

[1] PROTON AFFINITIES AND AGGREGATION STATES OF LITHIUM ALKOXIDES, PHENOLATES, ENOLATES, BETA-DICARBONYL ENOLATES, CARBOXYLATES, AND AMIDATES IN TETRAHYDROFURAN [J].

ARNETT, EM ;

MOE, KD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (19) :7288-7293

[2] STRUCTURE OF A SUPER BASE IN TETRAHYDROFURAN SOLUTION STUDIED BY LI-6, H-1 HOESY, CS-133, H-1 HOESY, AND MNDO - EVIDENCE FOR DISCRETE SPECIES RATHER THAN A MIXED AGGREGATE [J].

BAUER, W ;

LOCHMANN, L .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (19) :7482-7489

[3] SYNTHESIS AND X-RAY CRYSTAL-STRUCTURES OF THE ONE-DIMENSIONAL RIBBON CHAINS [MOBUT.BUTOH]-INFINITY AND THE CUBANE SPECIES [KOBU(T)]4 AND [RBOBUCT)]4 [J].

CHISHOLM, MH ;

DRAKE, SR ;

NAIINI, AA ;

STREIB, WE .

POLYHEDRON, 1991, 10 (03) :337-345

[4] STRUCTURE OF SODIUM TERT-BUTOXIDE - A RE-REFINEMENT [J].

DAVIES, JE ;

KOPF, J ;

WEISS, E .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1982, 38 (AUG) :2251-2253

[5] MASS SPECTRA OF LITHIOMETHYLTRIMETHYLSILANE AND LITHIUM T-BUTOXIDE [J].

HARTWELL, GE ;

BROWN, TL .

INORGANIC CHEMISTRY, 1966, 5 (07) :1257-&

[6] STRUCTURE AND REACTIVITY OF ALKALI-METAL ENOLATES [J].

JACKMAN, LM ;

LANGE, BC .

TETRAHEDRON, 1977, 33 (21) :2737-2769

[7] DEGENERATE TRANSESTERIFICATION OF 3,5-DIMETHYLPHENOLATE/3,5-DIMETHYLPHENYL ESTERS IN WEAKLY POLAR, APROTIC-SOLVENTS - REACTIONS OF AGGREGATES AND COMPLEX-INDUCED PROXIMITY EFFECTS [J].

JACKMAN, LM ;

PETREI, MM ;

SMITH, BD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (09) :3451-3458

[8] STRUCTURAL FACTORS CONTROLLING THE AGGREGATION OF LITHIUM PHENOLATES IN WEAKLY POLAR APROTIC-SOLVENTS [J].

JACKMAN, LM ;

SMITH, BD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (12) :3829-3835

[9] ESTER INTERCHANGE REACTION CATALYZED BY LANTHANOID TRI-2-PROPOXIDES [J].

OKANO, T ;

HAYASHIZAKI, Y ;

KIJI, J .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1993, 66 (06) :1863-1865

[10]

PAQUETTE LA, 1995, ENCY ORGANIC REAGENT, V6, P4189

← 1 2 →