Solid state synthesis of benzils at low-heating temperatures

被引：16

作者：

Zhou, YM ^{[1
]}

Ye, XR ^{[1
]}

Xin, XQ ^{[1
]}

机构：

[1] Nanjing Univ, State Key Lab Coordinat Chem, Inst Coordinat Chem, Nanjing 210093, Peoples R China

来源：

SYNTHETIC COMMUNICATIONS | 1999年 / 29卷 / 13期

关键词：

D O I：

10.1080/00397919908086222

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A simple and efficient method for the preparation of benzils through the solid state oxidation reaction of benzoins by FeCl3. 6H(2)O at low-heating temperatures(80 similar to 90 degrees C) is described. The oxidation conditions are mild. The products are easily separated with no pollutions produced.

引用

页码：2229 / 2234

页数：6

共 10 条

[1]

CLARKE HT, 1941, ORG SYNTH, V1, P87

[2]

Desiraju G. R., 1987, ORGANIC SOLID STATE

[3]

FIESER LF, 1967, REAGENTS ORGANIC SYN, V1, P734

[4]

Gomberg M., 1929, J AM CHEM SOC, V51, P2241

[5]

HO TL, 1972, SYNTHESIS-STUTTGART, P697

[6] A NEW REAGENT FOR THE OXIDATION OF ACYLOINS TO DIKETONES [J].

RIGBY, W .

JOURNAL OF THE CHEMICAL SOCIETY, 1951, (MAR) :793-795

[7] Solid state organic chemistry: Efficient reactions, remarkable yields, and stereoselectivity [J].

Toda, F .

ACCOUNTS OF CHEMICAL RESEARCH, 1995, 28 (12) :480-486

[8]

Ugai T., 1943, J PHARMACOL SOC JAPA, V63, P269

[9]

ZHANG GS, 1997, CHIN J SYNTH CHEM, V5, P218

[10]

1981, Patent No. 98203

← 1 →