Clay catalysis: Stork's alkylation and acylation of cyclohexanone without isolation of enamine

被引：7

作者：

Hammadi, M ^{[1
]}

Villemin, D ^{[1
]}

机构：

[1] UNIV CAEN,ISMRA,ECOLE NATL SUPER INGENIEURS CAEN,URA 480 CNRS,F-14050 CAEN,FRANCE

来源：

SYNTHETIC COMMUNICATIONS | 1996年 / 26卷 / 15期

关键词：

D O I：

10.1080/00397919608005225

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Cyclohexane and morpholine in the presence of KSF under azeotropic distillation gave 1-morpholinocyclohexene which is alkylated or acylated in situ without isolation of the enamine. The overall yield of these Stork's reactions are better or equivalent to those obtained by isolation of the enamine.

引用

页码：2901 / 2904

页数：4

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