Ionic liquids used for synthesis of supramolecular isomeric open-frameworks as photocatalysts for visible-light-driven degradation of organic dyes

被引:6
作者
Ji, Wen-Juan [1 ,2 ]
Hu, Man-Cheng [1 ]
Li, Shu-Ni [1 ]
Jiang, Yu-Cheng [1 ]
Zhai, Quan-Guo [1 ]
机构
[1] Shaanxi Normal Univ, Sch Chem & Chem Engn, Key Lab Macromol Sci Shaanxi Prov, Xian 710062, Shaanxi, Peoples R China
[2] Shanxi Normal Univ, Sch Chem & Mat Sci, Linfen 041004, Shanxi Province, Peoples R China
来源
CRYSTENGCOMM | 2014年 / 16卷 / 17期
基金
中国国家自然科学基金;
关键词
COORDINATION POLYMERS; SOLVENT; CRYSTAL; SELENIDOSTANNATES; POLYMORPHISM; NETWORKS; ANION;
D O I
10.1039/c4ce00014e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Two supramolecular isomeric anionic porous coordination frameworks synthesised using ion liquids contain similar linear trinuclear zinc motifs but exhibit quite different (4,7)- and (4,6)-connected topologies. Isomer 1 can degrade methylene blue (MB) effectively under UV-lightirradiation, but isomer 2 showed remarkable visible-light-driven degradation of diverse organic dyes.
引用
收藏
页码:3474 / 3477
页数:4
相关论文
共 36 条
[1]   SYNTHESIS, STRUCTURE, AND SPECTROSCOPIC PROPERTIES OF COPPER(II) COMPOUNDS CONTAINING NITROGEN SULFUR DONOR LIGANDS - THE CRYSTAL AND MOLECULAR-STRUCTURE OF AQUA[1,7-BIS(N-METHYLBENZIMIDAZOL-2'-YL)-2,6-DITHIAHEPTANE]COPPER(II) PERCHLORATE [J].
ADDISON, AW ;
RAO, TN ;
REEDIJK, J ;
VANRIJN, J ;
VERSCHOOR, GC .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1984, (07) :1349-1356
[2]   Ionic liquids and eutectic mixtures as solvent and template in synthesis of zeolite analogues [J].
Cooper, ER ;
Andrews, CD ;
Wheatley, PS ;
Webb, PB ;
Wormald, P ;
Morris, RE .
NATURE, 2004, 430 (7003) :1012-1016
[3]   Supramolecular isomerism in coordination polymers: Conformational freedom of ligands in [Co(NO3)(2)(1,2-bis(4-pyridyl)ethane)(1.5)](n) [J].
Hennigar, TL ;
MacQuarrie, DC ;
Losier, P ;
Rogers, RD ;
Zaworotko, MJ .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1997, 36 (09) :972-973
[4]   Triple-stranded helices and zigzag chains of copper(I) 2-ethylimidazolate: solvent polarity-induced supramolecular isomerism [J].
Huang, XC ;
Zhang, JP ;
Lin, YY ;
Chen, XM .
CHEMICAL COMMUNICATIONS, 2005, (17) :2232-2234
[5]   A new route to supramolecular isomers via molecular templating: Nanosized molecular polygons of copper(I) 2-methylimidazolates [J].
Huang, XC ;
Zhang, JP ;
Chen, XM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (41) :13218-13219
[6]   Solvent-induced supramolecular isomerism in silver(I) 2-methylimidazolate [J].
Huang, Xiao-Chun ;
Li, Dan ;
Chen, Xiao-Ming .
CRYSTENGCOMM, 2006, 8 (04) :351-355
[7]   The first ionothermal synthesis of a 3D ferroelectric metal-organic framework with colossal dielectric constant [J].
Ji, Wen-Juan ;
Zhai, Quan-Guo ;
Li, Shu-Ni ;
Jiang, Yu-Cheng ;
Hu, Man-Cheng .
CHEMICAL COMMUNICATIONS, 2011, 47 (13) :3834-3836
[8]   Induction in urothermal synthesis of chiral porous materials from achiral precursors [J].
Kang, Yao ;
Chen, Shumei ;
Wang, Fei ;
Zhang, Jian ;
Bu, Xianhui .
CHEMICAL COMMUNICATIONS, 2011, 47 (17) :4950-4952
[9]   Topological Difference in 2D Layers Steers the Formation of Rigid and Flexible 3D Supramolecular Isomers: Impact on the Adsorption Properties [J].
Kanoo, Prakash ;
Matsuda, Ryotaro ;
Kitaura, Ryo ;
Kitagawa, Susumu ;
Maji, Tapas Kumar .
INORGANIC CHEMISTRY, 2012, 51 (17) :9141-9143
[10]   Solvent-induced polymorphism of three-dimensional hydrogen-bonded networks of hexakis(4-carbamoylphenyl)benzene [J].
Kobayashi, K ;
Sato, A ;
Sakamoto, S ;
Yamaguchi, K .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (10) :3035-3045