Synthesis and kinetic cyclisation of quinine-derived oligomers

被引：18

作者：

Rowan, SJ ^{[1
]}

Brady, PA ^{[1
]}

Sanders, JKM ^{[1
]}

机构：

[1] UNIV CAMBRIDGE,CHEM LAB,CAMBRIDGE CB2 1EW,ENGLAND

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 33期

基金：

英国工程与自然科学研究理事会;

关键词：

D O I：

10.1016/0040-4039(96)01263-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis and kinetic cyclisations of a series of linear quinine oligomers are described. The distribution of cyclic oligomers is different from that observed in the corresponding thermodynamic cyclisation: cyclic tetramer is observed in the kinetic cyclisations, indicating that its absence under thermodynamic conditions is not due to any kinetic barrier to its formation. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：6013 / 6016

页数：4

共 6 条

[1]

BRADY PA, 1996, J CHEM SOC CHEM COMM, P319

[2] MACROCYCLIZATION UNDER KINETIC CONTROL - A THEORETICAL-STUDY AND ITS APPLICATION TO THE SYNTHESIS OF MACROCYCLIC POLY(THIOLACTONES) [J].