Infrared spectrum of solid isocyanic acid (HNCO): vibrational assignments and integrated band intensities

被引：77

作者：

Lowenthal, MS ^{[1
]}

Khanna, RK

Moore, MH

机构：

[1] Univ Maryland, Dept Chem & Biochem, College Pk, MD 20742 USA

[2] NASA, Goddard Space Flight Ctr, Greenbelt, MD 20771 USA

来源：

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 2002年 / 58卷 / 01期

关键词：

isocyanic acid; infrared spectroscopy; solid-state; absolute intensities; interstellar ices;

D O I：

10.1016/S1386-1425(01)00524-8

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

Infrared spectra of thin films of solid I-INCO condensed from the gas phase are characterized in terms of their vibrational frequencies, mode assignments, and integrated band intensities at low temperatures (similar to 20-145 K). Isocyanic acid is shown to react with water (H2O) and ammonia (NH3) even at low temperatures; consequently, it may be an important species in the chemistry of interstellar ices and comets. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：73 / 78

页数：6

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