Functionalization of saturated hydrocarbons by aprotic superacids .6. Effective regioselective monoformylation of adamantane in the presence of a hydride ion donor

被引：9

作者：

Akhrem, IS

Churilova, IM

Vitt, SV

Orlinkov, AV

Volpin, ME

机构：

[1] A. N. Nesmeyanov Inst. O., Russian Academy of Sciences, 117813 Moscow

来源：

RUSSIAN CHEMICAL BULLETIN | 1997年 / 46卷 / 03期

关键词：

functionalization of saturated hydrocarbons; formylation; adamantane; carbon monoxide; complexes of polyhalomethanes and aluminum halides; aprotic superacids; hydride ion donors; mass spectra;

D O I：

10.1007/BF02495402

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The inefficient formylation of adamantane by CO initiated by superacid systems based on polyhalomethanes and aluminum halides becomes selective in the presence of methylcyclopentane and affords 1-adamantanecarbaldehyde in an almost quantitative yield under mild conditions.

引用

页码：491 / 495

页数：5

共 19 条

[1] An effective formylation of adamantane with CO initiated by the aprotic organic superacid CBr4 center dot 2AlBr(3) under mild conditions [J].