Decomposition of ethyl chloride and vinyl chloride in an electron beam generated plasma reactor

被引:6
作者
Vitale, SA
Hadidi, K
Cohn, DR
Bromberg, L
机构
[1] MIT Plasma Fusion Center, Cambridge, MA 02139
来源
RADIATION PHYSICS AND CHEMISTRY | 1997年 / 49卷 / 04期
关键词
D O I
10.1016/S0969-806X(96)00177-6
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
An electron beam generated plasma reactor is used to decompose low concentrations of ethyl chloride (EC) and vinyl chloride (VC) in atmospheric pressure air streams. The energy requirements for 90% decomposition of each compound are reported as a function of inlet concentration. VC decomposition is enhanced by chlorine radical reactions. Both the EC and VC reactions seem to be inhibited by electron scavenging decomposition products. A simple analytic expression is used for fitting decomposition data where inhibition effects are important. (C) 1997 Elsevier Science Ltd.
引用
收藏
页码:421 / 428
页数:8
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