Redox chemistry of cerocene: the first heterobimetallic organolanthanide complex

被引：12

作者：

Reissmann, U

Lameyer, L

Stalke, D

Poremba, P

Edelmann, FT

机构：

[1] Univ Magdeburg, Inst Chem, D-39106 Magdeburg, Germany

[2] Univ Wurzburg, Inst Anorgan Chem, D-97074 Wurzburg, Germany

[3] Univ Gottingen, Inst Anorgan Chem, D-37077 Gottingen, Germany

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 18期

关键词：

D O I：

10.1039/a903954f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first heterobimetallic organolanthanide complex containing two different rare earth elements, [Yb(thf)(6)][Ce- (cot''')(2)](2) 2 [cot''' = eta(8)-1,3,6-(Me3Si)(3)C8H5], has been prepared by reacting neutral [Ce(cot''')(2)] with Yb metal in THF; the crystal structure of 2 consists of separated [Yb(thf)(6)](2+) and [Ce(cot''')(2)](-) ions.

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页码：1865 / 1866

页数：2

相关论文

共 29 条

[1] ELECTRONIC-STRUCTURE OF ORGANOMETALLIC COMPLEXES INVOLVING F-ELECTRONS .1. URANOCENE [J].

AMBERGER, HD ;

FISCHER, RD ;

KANELLAKOPULOS, B .

THEORETICA CHIMICA ACTA, 1975, 37 (02) :105-127

[2]

[Anonymous], PROGRAM CRYSTAL STRU

[3] THE 1ST HIGH-RESOLUTION DIRECT NMR OBSERVATION OF AN F-BLOCK ELEMENT [J].

AVENT, AG ;

EDELMAN, MA ;

LAPPERT, MF ;

LAWLESS, GA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (09) :3423-3425

[4] SYNTHESIS AND STRUCTURE OF TRIPHENYLMETHYL DERIVATIVES OF YTTERBIUM [YB(THF)(6)](2+)[PH(3)C](2)(-) AND [(THF)(4)YB(MU-CL)(2)YB(THF)(4)](2+)[PH(3)CL](2)(-) [J].

BOCHKAREV, LN ;

MOLOSNOVA, NE ;

ZAKHAROV, LN ;

FUKIN, GK ;

YANOVSKY, AI ;

STRUCHKOV, YT .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1995, 485 (1-2) :101-107

[5] A RELATIVISTIC LCAO HARTREE-FOCK-SLATER INVESTIGATION OF THE ELECTRONIC-STRUCTURE OF THE ACTINOCENES TH(COT)2, PA(COT)2, U(COT)2, NP(COT)2, PU(COT)2 [J].

BOERRIGTER, PM ;

BAERENDS, EJ ;

SNIJDERS, JG .

CHEMICAL PHYSICS, 1988, 122 (03) :357-374

[6] STRUCTURES OF ORGANO-F-ELEMENT COMPOUNDS DIFFERING IN THE OXIDATION-STATE OF THE CENTRAL METAL - CRYSTAL-STRUCTURES OF BIS([8]ANNULENE) COMPLEXES OF CERIUM(IV), YTTERBIUM(III), AND URANIUM(III) [J].

BOUSSIE, TR ;

EISENBERG, DC ;

RIGSBEE, J ;

STREITWIESER, A ;

ZALKIN, A .

ORGANOMETALLICS, 1991, 10 (06) :1922-1928

[7] ELECTRONIC-STRUCTURE AND SPECTRA OF URANOCENE [J].

CHANG, AHH ;

PITZER, RM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (07) :2500-2507

[8] RESONANCE RAMAN-SPECTROSCOPY OF URANOCENE - OBSERVATION OF AN ANOMALOUSLY POLARIZED ELECTRONIC BAND AND ASSIGNMENT OF ENERGY-LEVELS [J].

DALLINGER, RF ;

STEIN, P ;

SPIRO, TG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (25) :7865-7870

[9] GROUND-STATE CALCULATIONS OF DI-PI-CYCLOOCTATETRAENE CERIUM [J].

DOLG, M ;

FULDE, P ;

KUCHLE, W ;

NEUMANN, CS ;

STOLL, H .

JOURNAL OF CHEMICAL PHYSICS, 1991, 94 (04) :3011-3017

[10] FORMALLY TETRAVALENT CERIUM AND THORIUM COMPOUNDS - A CONFIGURATION-INTERACTION STUDY OF CEROCENE CE(C8H8)(2) AND THOROCENE TH(C8H8)(2) USING ENERGY-ADJUSTED QUASI-RELATIVISTIC AB-INITIO PSEUDOPOTENTIALS [J].

DOLG, M ;

FULDE, P ;

STOLL, H ;

PREUSS, H ;

CHANG, A ;

PITZER, RM .

CHEMICAL PHYSICS, 1995, 195 (1-3) :71-82