Acid-catalyzed rearrangement of 1,3-bishomocubanone -: Formation of chloro and tosyloxy substituted tricyclo[5.2.1.04,8]dec-2-ene ring system

被引：1

作者：

Awano, K

Ogino, T

机构：

[1] Nagaoka Coll Technol, Dept Mat Engn, Nagaoka, Niigata 9408532, Japan

[2] Niigata Univ, Fac Educ, Dept Chem, Niigata 9502181, Japan

来源：

NIPPON KAGAKU KAISHI | 1999年 / 04期

关键词：

D O I：

10.1246/nikkashi.1999.287

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

4-Phenylpentacyclo[5.3.0.0(2,5).0(3,9).0(4,8)] decan-6-one underwent acid-catalyzed rearrangement to give two isomeric chloro or tosyloxy derivatives having tricycle [5.2.1.0(4.8)] dec-2-ene ring system, according to the type of the acid, Lewis acid containing chlorine or TsOH.

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页码：287 / 291

页数：5

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