Enantiospecific chemisorption of small molecules on intrinsically chiral Cu surfaces

被引：47

作者：

Bhatia, B ^{[1
]}

Sholl, DS ^{[1
]}

机构：

[1] Carnegie Mellon Univ, Dept Chem Engn, Pittsburgh, PA 15213 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 47期

关键词：

chemisorption; density functional calculations; enantioselectivity; surface chemistry;

D O I：

10.1002/anie.200501655

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Stepping up: Density functional calculations indicate that small molecules, such as propylene oxide, chemisorb in an enantiospecific manner on intrinsically chiral, stepped Cu surfaces. As an example, the preferential adsorption configurations for the (S)- (right) and (R)-amino(fluoro)methoxy species (left) on Cu(874)S are shown. (Figure Presented). © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：7761 / 7764

页数：4

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