Synthesis and revision of the stereochemistry of a cyclopentenone natural product isolated from ascomycete strain A23-98

被引：29

作者：

Bickley, JF

Roberts, SA

Santoro, AG

Snape, TJ

机构：

[1] Univ Liverpool, Charterhouse Therapeut Labs, Liverpool L69 7ZD, Merseyside, England

[2] Univ Liverpool, Dept Chem, Liverpool L69 7ZD, Merseyside, England

[3] Univ Roma Tor Vergata, Dept Biol, I-100133 Rome, Italy

来源：

TETRAHEDRON | 2004年 / 60卷 / 11期

关键词：

2-alkenyl-4,5-dihydroxycyclopent-2-enones; Stille-type reaction; cis-Tributylpropenyl Stannane;

D O I：

10.1016/j.tet.2004.01.045

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The 2-propenyl-4,5-dihydroxycyclopent-2-enones 4, 10 and 14 have been synthesised in optically active form. NMR data suggest the compounds 10 and 14 (but not 4) correspond to compounds isolated from ascomycete strain A23-98. (C) 2004 Elsevier Ltd. All rights reserved.

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页码：2569 / 2576

页数：8

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