Unexpected polymeric string formation between Ag(I) and a homoleptic thioether cage:: synthesis and crystal structure of [R,R′-S6tricosane] and {[Ag(R,R′-S6hexacosane)]TsO}∞

被引：21

作者：

Alberto, R ^{[1
]}

Angst, D

Abram, U

Ortner, K

Kaden, TA

Schubiger, AP

机构：

[1] Paul Scherrer Inst, Ctr Radiopharm, CH-5232 Villigen, Switzerland

[2] Forschungszentrum Rossendorf EV, Inst Radiochem, D-01062 Dresden, Germany

[3] Univ Basel, Dept Inorgan Chem, CH-5067 Basel, Switzerland

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 16期

关键词：

D O I：

10.1039/a903455b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The large cavity homoleptic thioether cages [R,R'-S(6)tricosane] (1-hydroxymethyl-9-methyl-3,7,11,15,18,22-hexathiabicyclo[7.7.7]tricosane) (1) and [R,R'-S(6)hexacosane] (1-hydroxymethyl-10-methyl-3,8,12,17,20,25-hexathiabicyclo-[8.8.8]hexacosane) (2) have been synthesized and the structures of 1 and of the complex {[Ag(2)]TsO}(infinity) have been elucidated, the latter showing a polymeric string structure with Ag+ coordinated by three different cages.

引用

页码：1513 / 1514

页数：2

共 19 条

[1] Silver(I) complexes of the derivatized crown thioether ligands 3,6,9,12,15,18-hexathianonadecanol and 3,6,9,13,16,19-hexathiaicosanol. Determination of stability constants and the crystal structures of [Ag(19-aneS6-OH)][CF3SO3] and [Ag(20-aneS6-OH)][BF4] [J].

Alberto, R ;

Nef, W ;

Smith, A ;

Kaden, TA ;

Neuburger, M ;

Zehnder, M ;

Frey, A ;

Abram, U ;

Schubiger, PA .

INORGANIC CHEMISTRY, 1996, 35 (11) :3420-3427

[2] NICKEL THIOETHER CHEMISTRY - SYNTHESES OF NICKEL(II) COMPLEXES OF TETRA-THIA AND PENTA-THIA MACROCYCLIC LIGANDS - THE SINGLE-CRYSTAL STRUCTURES OF [NI([16]ANES4)(OH2)2][BF4]2 AND [NI([15]ANES5)][PF6]2 ([16]ANES4 = 1,5,9,13-TETRATHIACYCLOHEXADECANE, [15]ANES5 = 1,4,7,10,13-PENTATHIACYCLOPENTADECANE) [J].

BLAKE, AJ ;

HALCROW, MA ;

SCHRODER, M .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1992, (19) :2803-2808

[3] SILVER THIOETHER CHEMISTRY - SYNTHESIS, X-RAY CRYSTAL-STRUCTURE AND REDOX PROPERTIES OF [AG([18]ANES6)]+ ([18]ANES6=1,4,7,10,13,16-HEXATHIACYCLOOCTADECANE) [J].

BLAKE, AJ ;

GOULD, RO ;

HOLDER, AJ ;

HYDE, TI ;

SCHRODER, M .

POLYHEDRON, 1989, 8 (04) :513-518

[4]

Blake AJ, 1997, CHEM COMMUN, P1943

[5] CHEMISTRY OF THIOETHER MACROCYCLIC COMPLEXES [J].

Blake, Alexander J. ;

Schroeder, Martin .

ADVANCES IN INORGANIC CHEMISTRY <D>, 1990, 35 :1-80

[6] CROWN THIOETHER CHEMISTRY - THE SILVER(I) COMPLEXES OF TRITHIA-9-CROWN-3, TRITHIA-12-CROWN-3, AND HEXATHIA-18-CROWN-6 [J].

BLOWER, PJ ;

CLARKSON, JA ;

RAWLE, SC ;

HARTMAN, JR ;

WOLF, RE ;

YAGBASAN, R ;

BOTT, SG ;

COOPER, SR .

INORGANIC CHEMISTRY, 1989, 28 (21) :4040-4046

[7] SYNTHESIS OF SULFUR-CONTAINING MACROCYCLES USING CESIUM THIOLATES [J].

BUTER, J ;

KELLOGG, RM .

JOURNAL OF ORGANIC CHEMISTRY, 1981, 46 (22) :4481-4485

[8]

DIEBLER H, 1969, Pure and Applied Chemistry, V20, P93, DOI 10.1351/pac196920010093

[9] OXATHIA-MACROBICYCLIC DIAMINES AND THEIR CRYPTATES [J].

DIETRICH, B ;

LEHN, JM ;

SAUVAGE, JP .

JOURNAL OF THE CHEMICAL SOCIETY D-CHEMICAL COMMUNICATIONS, 1970, (17) :1055-&

[10] ENCAPSULATED METAL-IONS - SYNTHESIS, STRUCTURE, AND SPECTRA OF NITROGEN SULFUR LIGAND ATOM CAGES CONTAINING COBALT(III) AND COBALT(II) [J].

GAHAN, LR ;

HAMBLEY, TW ;

SARGESON, AM ;

SNOW, MR .

INORGANIC CHEMISTRY, 1982, 21 (07) :2699-2706

← 1 2 →