Creation of a chain-like cationic iron species in montmorillonite as a highly active heterogeneous catalyst for alkane oxygenations using hydrogen peroxide

被引：49

作者：

Ebitani, K ^{[1
]}

Ide, M ^{[1
]}

Mitsudome, T ^{[1
]}

Mizugaki, T ^{[1
]}

Kaneda, K ^{[1
]}

机构：

[1] Osaka Univ, Grad Sch Engn Sci, Dept Sci & Chem Engn, Osaka 5608531, Japan

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 07期

关键词：

D O I：

10.1039/b200255h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A chain-like Fe3+ species containing an Fe-O-Fe unit has been prepared within the interlayer space of a montmorillonite, which showed a very high catalytic activity (turnover frequency 386 h(-1) and turnover number 23 200) for the oxidation of cyclohexane with H2O2, affording cyclohexyl hydroperoxide as a major product.

引用

页码：690 / 691

页数：2

共 16 条

[1] THE SELECTIVE FUNCTIONALIZATION OF SATURATED-HYDROCARBONS - GIF CHEMISTRY [J].

BARTON, DHR ;

DOLLER, D .

ACCOUNTS OF CHEMICAL RESEARCH, 1992, 25 (11) :504-512

[2] Simple and clean synthesis of 9,9-bis[4-(2-hydroxyethoxy)phenyl]fluorene from the aromatic alkylation of phenoxyethanol with fluoren-9-one catalysed by titanium cation-exchanged montmorillonite [J].

Ebitani, K ;

Kawabata, T ;

Nagashima, K ;

Mizugaki, T ;

Kaneda, K .

GREEN CHEMISTRY, 2000, 2 (04) :157-160

[3] BIOMIMETIC OXIDATION STUDIES .5. MECHANISTIC ASPECTS OF ALKANE FUNCTIONALIZATION WITH FE,FE2O, AND FE4O2 COMPLEXES IN THE PRESENCE OF HYDROGEN-PEROXIDE [J].

FISH, RH ;

KONINGS, MS ;

OBERHAUSEN, KJ ;

FONG, RH ;

YU, WM ;

CHRISTOU, G ;

VINCENT, JB ;

COGGIN, DK ;

BUCHANAN, RM .

INORGANIC CHEMISTRY, 1991, 30 (15) :3002-3006

[4] CHARACTERIZATION OF IRON OXIDE-DISPERSED ACTIVATED CARBON-FIBERS WITH FE K-EDGE XANES AND EXAFS AND WITH WATER-ADSORPTION [J].

KANEKO, K ;

KOSUGI, N ;

KURODA, H .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1989, 85 :869-&

[5] CATALYSIS OF ORGANIC-REACTIONS BY INORGANIC SOLIDS [J].

LASZLO, P .

ACCOUNTS OF CHEMICAL RESEARCH, 1986, 19 (04) :121-127

[6] MODELS FOR NONHEME IRON OXYGENASES - A HIGH-VALENT IRON OXO INTERMEDIATE [J].

LEISING, RA ;

BRENNAN, BA ;

QUE, L ;

MUNCK, E .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (10) :3988-3990

[7] Formation of ultrathin multilayer and hydrated gel from montmorillonite and linear polycations [J].

Lvov, Y ;

Ariga, K ;

Ichinose, I ;

Kunitake, T .

LANGMUIR, 1996, 12 (12) :3038-3044

[8] MU-OXO-BRIDGED DIIRON(III) COMPLEXES AND H2O2 - MONOOXYGENASE-LIKE AND CATALASE-LIKE ACTIVITIES [J].

MENAGE, S ;

VINCENT, JM ;

LAMBEAUX, C ;

FONTECAVE, M .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1994, (14) :2081-2084

[9] Highly efficient utilization of hydrogen peroxide for selective oxygenation of alkanes catalyzed by diiron-substituted polyoxometalate precursor [J].

Mizuno, N ;

Nozaki, C ;

Kiyoto, I ;

Misono, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (36) :9267-9272

[10] Powerful redox molecular sieve catalysts for the selective oxidation of cyclohexane in air [J].

Raja, R ;

Sankar, G ;

Thomas, JM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (50) :11926-11927

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