The range in static stereochemistry of the cation distortion isomers of the [Cu(chelate)2Cl]+ cation, where chelate = bipy, phen or bipyam.: The low temperature crystal structure (150 K) of [Cu(bipy)2Cl][PF6]•H2O and [Cu(phen)2Cl][BPh4]

被引：43

作者：

Brophy, M

Murphy, G

O'Sullivan, C

Hathaway, B ^{[1
]}

Murphy, B

机构：

[1] Natl Univ Ireland Univ Coll Cork, Dept Chem, Cork, Ireland

[2] Univ Wales, Dept Chem, Cardiff CF1 3TB, S Glam, Wales

来源：

POLYHEDRON | 1999年 / 18卷 / 05期

关键词：

low temperature; static copper(II) stereochemistries; cation distortion isomer;

D O I：

10.1016/S0277-5387(98)00212-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Low temperature crystallography (150 K) has been used to confirm that the two extreme [Cu(chelate)(2)Cl][Y] stereochemistries of 3 [Cu(bipy)(2)Cl][PF6]. H2O, trigonal bipyramidal and 6 [Cu(phen)(2)Cl][BPh4], trigonal bipyramidal distorted square based pyramidal, are genuine and static stereochemistries of the copper(II) ion. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：611 / 615

页数：5

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