Synthesis of porritoxin

被引：12

作者：

Cornella, I ^{[1
]}

Kelly, TR ^{[1
]}

机构：

[1] Boston Coll, Eugene F Merket Chem Ctr, Dept Chem, Chestnut Hill, MA 02467 USA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2004年 / 69卷 / 06期

关键词：

D O I：

10.1021/jo0356210

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A total synthesis following the sequence in Scheme I confirms that porritoxin possesses revised structure 3, not the originally assigned 1. A key reaction was the use of iron pentacarbonyl to formylate an aryllithium when DMF and methyl formate proved insufficiently reactive.

引用

页码：2191 / 2193

页数：3

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