(Isocyanide)gold(I) thiosalicylates: Supramolecular assembly based on both auriophilic and hydrogen bonding

被引：98

作者：

Schneider, W ^{[1
]}

Bauer, A ^{[1
]}

Schmidbaur, H ^{[1
]}

机构：

[1] TECH UNIV MUNCHEN WEIHENSTEPHAN,INST ANORGAN CHEM,D-85747 GARCHING,GERMANY

来源：

ORGANOMETALLICS | 1996年 / 15卷 / 26期

关键词：

D O I：

10.1021/om960682s

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of(RNC)AuCl[R=tert-butyl (1a), mesityl (1b)] with sodium thiosalicylate in the two-phase system water/dichloromethane gives high yields of the corresponding (isocyanide)gold(I) thiosalicylates (2a,b). The solid-state structures of 2a,b have been determined by X-ray diffraction studies. The supramolecular structure of both compounds is governed by Au-Au interactions [2a, Au-Au 3.157(2) Angstrom; 2b, Au-Au 3.3186(5) Angstrom] and hydrogen bonding through the carboxylic acid groups.

引用

页码：5445 / 5446

页数：2

共 22 条

[1] PYRIDINE ADDUCTS OF THE GOLD HALIDES .2. SYNTHESIS, PROPERTIES, AND CRYSTAL-STRUCTURE OF AUCL.NC5H5 AND AUI.NC5H5 [J].

ADAMS, HN ;

HILLER, W ;

STRAHLE, J .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1982, 485 (02) :81-91

[2] CRYSTAL-STRUCTURE OF IODO(TETRAHYDROTHIOPHENE)GOLD(I) AT 200 K - A COMPOUND WITH AN INFINITE ARRAY OF GOLD GOLD BONDS [J].

AHRLAND, S ;

NOREN, B ;

OSKARSSON, A .

INORGANIC CHEMISTRY, 1985, 24 (09) :1330-1333

[3] METAL-METAL INTERACTIONS IN CHAIN COMPOUNDS OF GOLD(I) - SYNTHESES AND CRYSTAL-STRUCTURES OF CHLOROTETRAHYDROTHIOPHENEGOLD(I), BROMOTETRAHYDROTHIOPHENEGOLD(I) AND IODOTETRAHYDROSELENOPHENEGOLD(I) [J].

AHRLAND, S ;

DREISCH, K ;

NOREN, B ;

OSKARSSON, A .

MATERIALS CHEMISTRY AND PHYSICS, 1993, 35 (3-4) :281-289

[4] N-15 and P-31 NMR studies of cyano (trialkyl/triaryl)phosphine gold(I) complexes [J].

Akhtar, MN ;

Gazi, IH ;

Isab, AA ;

AlArfaj, AR ;

Wazeer, MIM ;

Hussain, MS .

JOURNAL OF COORDINATION CHEMISTRY, 1995, 36 (02) :149-157

[5] Self-assembly of [(Me(2)PhP)(2)Au](+)[Au(GeCl3)(2)](-) into linear ion quadruples with an unusual [+--+] sequence [J].

Bauer, A ;

Schmidbaur, H .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (22) :5324-5325

[6] PYRIDINE ADDUCTS OF GOLD HALIDES .3. PREPARATION, PROPERTIES, AND CRYSTAL-STRUCTURE OF 2 MODIFICATIONS OF AUBR.NC5H5 [J].

CONZELMANN, W ;

HILLER, W ;

STRAHLE, J ;

SHELDRICK, GM .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1984, 512 (05) :169-176

[7] 1,1'-BIS(DIPHENYLPHOSPHINO)BICYCLOPROPYL - SYNTHESIS, PROPERTIES, PRECURSORS, DERIVATIVES, AND METAL-COMPLEXES [J].

DZIWOK, K ;

LACHMANN, J ;

WILKINSON, DL ;

MULLER, G ;

SCHMIDBAUR, H .

CHEMISCHE BERICHTE, 1990, 123 (03) :423-431

[8] (TERT-BUTYL ISOCYANIDE)CHLOROGOLD(I) [J].

EGGLESTON, DS ;

CHODOSH, DF ;

WEBB, RL ;

DAVIS, LL .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1986, 42 :36-38

[9] Auracarboranes with and without Au-Au interactions: An unusually strong aurophilic interaction [J].

Harwell, DE ;

Mortimer, MD ;

Knobler, CB ;

Anet, FAL ;

Hawthorne, MF .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (11) :2679-2685

[10] SOLID-STATE STRUCTURE AND SOLUTION EQUILIBRIA OF CYANO(TRIETHYLPHOSPHINE)GOLD(I) [J].

HORMANN, AL ;

SHAW, CF ;

BENNETT, DW ;

REIFF, WM .

INORGANIC CHEMISTRY, 1986, 25 (22) :3953-3957

← 1 2 3 →